When is an Oil Not an Oil?

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Kevin Cameron has been writing about motorcycles for nearly 50 years, first for <em>Cycle magazine</em> and, since 1992, for <em>Cycle World</em>.

Kevin Cameron has been writing about bikes for practically 50 years, first for <em>Cycle journal</em> and, since 1992, for <em>Cycle World</em>. (Robert Martin/)

Engineers had been entranced with the physics of full-fluid-film lubrication of the type that makes the plain bearings in trendy engines workable. They weren’t so blissful once they tried to use the identical physics to the lubrication of energy gearing. Their tried-and-true equations indicated that such gearing, working at very excessive tooth-to-tooth pressures, couldn’t probably work. Metallic-to-metal contact ought to happen, inflicting fast put on adopted by early failure.

However gears do work. Nicely-made, surface-hardened metal energy gearing survives over lengthy intervals of operation at tooth-to-tooth pressures as excessive as 100,000 psi. In any trendy bike engine, energy passes via a pair of major gears from crankshaft to gearbox enter shaft, after which via any of the six pairs of gears within the common 6-speed gearbox to the output sprocket or shaft. I’ve by no means even seen a major gear failure (apart from one brought on by lack of lubricant).

A 1949 paper by Russian scientist A.N. Grubin described what he referred to as an “elastohydrodynamic” impact (EHD), with a really skinny layer of lubricant in some way trapped between the elastically deforming surfaces of laborious gear enamel. What may probably trigger a liquid to stay in such a spot, slightly than be immediately squirted out?

Pressures between transmission gear teeth can reach 100,000 psi.

Pressures between transmission gear enamel can attain 100,000 psi. (Jeff Allen /)

The colours we see when oil types a movie on the floor of water come from interference, because the various thickness of the movie trigger some mild frequencies to intrude with one another as they’re mirrored from the highest and backside of the oil movie. The identical impact, however brought on by clear floor oxide layers, produces the colour bands seen on welded titanium exhaust pipes. This similar impact was used at Imperial Faculty, London, to measure the elastohydrodynamic oil movie between surfaces closely loaded in opposition to one another. Researchers discovered movie thicknesses of 0.1 to 1.0 micron.

How thick is a mono-molecular layer of oil? A basic experiment attributed to the ever-curious Benjamin Franklin supplies the reply. Dusting a non-wettable powder over the water floor permits the experimenter to simply see the clear space coated by a spreading oil movie after putting a drop on the water’s floor. As soon as it has unfold so far as it may possibly and has a uniform look it’s simply arithmetic to match the amount of the unique oil drop (measure its diameter simply earlier than placing it on the water) with the amount of the movie, which is simply its space multiplied occasions what we need to know, which is its thickness. In a single case, the reply was .017 micron.

Evaluating that with the EHD movie thickness vary measured at Imperial Faculty, we discover this to be between 6 and 60 molecular thicknesses.

Subsequent query: what can probably enable that oil to stay between two surfaces which are exerting such super strain to squeeze it out? A method to have a look at this could be to say that the viscosity of the liquid is in some way massively elevated by such nice strain. The calculation confirmed that the oil’s viscosity had elevated by roughly 5 orders of magnitude (that’s, by an element of 100,000, or ten to the fifth energy).

We all know that hydrocarbon molecules take the type of lengthy chains of carbon atoms, every one bonded to hydrogen atoms. For hydrocarbons within the lubricating oil vary, there are roughly between 20 and 70 carbon atoms, making the chains fairly lengthy. What has been found is that underneath nice strain, oil molecules self-align to change into parallel with one another. As this occurs in oil trapped between laborious surfaces, their interplay with one another more and more assumes the character of a crystalline strong. In a crystal, the atoms kind extremely common ranks and rows, every bonded by electrical forces to its neighbors. One thing related occurs when rubber is significantly deformed – its lengthy chain molecules align with each other and could also be attracted to one another by short-range forces: the rubber now assumes the properties of a crystalline strong.

Laptop simulations of molecular-level oil conduct in such unusual circumstances point out that the one means any particular person molecule can escape the zone of excessive strain is end-wise – a tough course of. A witty researcher has given this the title “reptation” (snaking).

This molecular alignment and confinement appears to be the mechanism that permits closely loaded gears to outlive via lengthy and productive lives.

On the 2 events after I’ve ridden in helicopters (It was a John Wayne/LAX commuter service) I’ve discovered myself fascinated with the roughly 100-to-one rpm discount from the quick spinning generators to the primary rotor, beating its means via the air at 300 or so rpm. Helicopter gearboxes are extremely refined items of equipment.

Good factor oils simply occur to method a strong crystalline state as they get pinched between the large variety of gear enamel that serve the human undertaking.

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